CONTENTS

Preface

Organizing committee

International advisory board

International scientific committee

Local advisory board

Local organizing committee

Supporting organizations

Supporting organizations for technical excursion

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I. Heterogeneous catalysis of CO₂

Heterogeneous catalytic reactions with CO₂: Status and perspectives

G. Centi and S. Perathoner

Chemicals from CO₂ via heterogeneous catalysis at moderate conditions

Y. Sun

Synthetic hydrocarbon fuels and CO₂ utilization

G. Schaub, D. Unruh and M. Rohde

Design of copper based hybrid catalysts for CO₂ hydrogenation

Y.-K. Park, J.-K. Jeon and S.-K. Ihm

Plasma enhanced preparation of highly dispersed Ni/Al₂O₃ catalyst for CO₂ reforming of Methane

D. Cheng, Q. Xia. and C. Liu

Synthesis of dimethyl carbonate by transesterification over CaO/carbon solid base catalysts

T. Wei, M. Wang, W. Wei, Y. Sun and B. Zhong

The synthesis of clean fuels by F-T reaction from CO₂ rich biosyngas

J.-S. Ryu, K.-W. Lee, M.-J. Choi and H.-S. Yoo

Reduction of carbon dioxide using metal powders

H. Katsumata, K. Matsushita, S. Kaneco, T. Suzuki and K. Ohta

Catalytic hydrogenation of CO₂ to methanol over Pd/ZnO: Metalsupport interaction

C.-H. Kim, J.S. Lee and D.L. Trimm

CAMERE Process for methanol synthesis from CO₂ hydrogenation

O.-S. Joo, K.-D. Jung and Y. Jung

Product distribution analysis for catalytic reduction of CO₂ in a bench scale fixed bed reactor

S.-B. Lee, J.-S. Kim, W.-Y. Lee, K.-W. Lee, and M.-J. Choi

Process evaluation of biomass to liquid fuel production system with gasification and liquid fuel synthesis

T. Minowa, T. Hanaoka and S. Yokoyama

Novel catalysts for gasification of biomass with high energy efficiency

T. Miyazawa, M. Asadullah, M. Nurunnabi, B. Li, K. Kunimori and K. Tomishige

Improving carbon utilization in biomass conversion to synthetic hydrocarbons via Fischer-Tropsch synthesis

D. Unruh, M. Rohde and G. Schaub

Fischer-Tropsch synthesis with CO₂-containing syngas from biomass – Kinetic analysis of fixed bed reactor model experiments

M. Rohde, D. Unruh, P. Pias, K.-W. Lee and G. Schaub

Hydrogen production from woody biomass by novel gasification using CO₂ sorbent

T. Hanaoka, S. Fujimoto, T. Yoshida, K. Kamei, M. Harada, Y. Suzuki, S. Yokoyama and T. Minowa

A feasibility study of synthesis of oxygenates directly from methane and carbon dioxide using dielectric-barrier discharges

J. Wang, C. Liu and B. Eliassion

Synthesis gas production from CO₂ and H₂O with nonthermal plasma

S. Futamura and H. Kabashima

CO₂ reduction by blast furnace top gas recycling combined with waste hydrocarbon gasification

J.-O. Choi and J.-G. Kim

Microwave–assisted reactions of oxiranes with carbon dioxide in ionic liquids

M. Nüchter, B. Ondruschka, J. Hoffmann and A. Tied

CO₂ reforming of n-heptane on a Ni/Al₂O₃ catalyst

K.J. Puolakka and A.O.I. Krause

Hexaaluminate catalysts of the novel process of syngas production through catalytic oxidation and steam-CO₂ reforming of methane

O. Yokota, T. Tanaka, Z. Hou and T. Yashima

Redox behavior of Cu-ferrite for CO₂ decomposition

H.C. Shin, S.C. Choi, C. S. Kim, O.-S. Joo and K.-D. Jung

CO₂ reforming by CH₄ over Ni-YSZ modified catalysts

D.J. Moon, J.W. Ryu, D.M. Kang, B.G. Lee and B.S. Ahn

The interaction between CO₂ and CH₄ on Ru-Co-catalysts

L.B. Shapovalova, G.D. Zakumbaeva, I.A. Shlygina and A.A. Shyrtbaeva.

Selective formation of light olefins by the cracking of heavy naphtha over acid catalysts

S.Y. Han, C.W. Lee, J.R. Kim, N.S. Han, W.C. Choi, C.-H. Shin and Y.-K. Park

Effect of additives and a preparation method on catalytic activity of Cu/ZnO/ZrO₂ system in the carbon dioxide hydrogenation to methanol

J. Słoczyński, R. Grabowski, A. Kozłowska, M. Lachowska and J. Skrzypek

Selective formation of ethylene carbonate from ethylene glycol and carbon dioxide over CeO₂-ZrO₂ solid solution catalysts

K. Tomishige, H. Yasuda, M. Nurunnabi, B. Li and K. Kunimori

Effects of palladium particle size in hydrogenation of carbon dioxide to methanol over Pd/ZnO catalysts

D. Lee, J.-Y. Lee and J.S. Lee

Ga, Mn and Mg promoted copper/zinc/zirconia – catalysts for hydrogenation of carbon dioxide to methanol

M. Lachowska and J. Skrzypek

Catalytic hydrogenation of carbon dioxide to light olefins in a fluidized bed reactor

J.-S. Kim, S.-B. Lee, M.-J. Choi, Y.K. and K.-W. Lee

Synthesis of dimethyl carbonate from CH₃OH and CO₂ with Ce_1-xZr_xO₂ catalysts

G.B. Han, N.K. Park, J.H. Jun, W.C. Chang, B.G. Lee, B.S. Ahn, S.O. Ryu and T.J. Lee

The effect of catalyst pore structure change into the selectivity and conversion of CO₂ hydrogenation over Fe-K/γ-Al₂O₃

S.-C. Lee, J.-H. Jang, B.-Y. Lee, T. Jeong and S.-J. Choung

Tri-reforming of CH₄ using CO₂ for production of synthesis gas to dimethyl ether

S.-H. Lee, W. Cho, W.-S. Ju, Y.-S. Baek, J.-S. Chang and S.-E. Park

Carbon dioxide reduction technology with SOFC system

D.J. Moon, J.W. Ryu and S.D. Lee

Synthesis of dimethyl carbonate from urea and methanol over metal oxides

M. Wang, N. Zhao, W. Wei and Y. Sun

Development of heterogeneous catalyst system for esterification of free fatty acid contained in used vegetable oil

H.-J. Kim, B.-S. Kang, M.-J. Kim, D.-K. Kim, J.-S. Lee and K.-Y. Lee

Investigation of synthesis gas production from natural gas and CO₂ by microwave plasma technology

W. Cho, W.-S. Ju, S.-H. Lee, Y.-S. Baek and Y.C. Kim

CO₂ hydrate kinetics in electrolyte solutions containing clay minerals

J. Lee, J. Park, M.-K. Chun, K. Lee, J.-H. Lee, J.-M. Kang and H. Lee

II. Homogemeous catalysis of CO₂

New catalysts for the conversion of urea into carbamates and carbonates with C1 and C2 alcohols

M. Aresta, A. Dibenedetto, C. Devita, O.A. Bourova and O.N. Chupakhin

Group 5 (V, Nb and Ta) element-alkoxides as catalysts in the trans-esterification of ethylene-carbonate with methanol, ethanol and allyl alcohol

M. Aresta, A. Dibenedetto and C. Pastore

Hydroformylation with carbon dioxide using ionic liquid media

K. Tominaga and Y. Sasaki

Ionic liquid-derived imidazolium metal halides for the coupling reaction of ethylene oxide and CO₂

O.-S. Kwon, J. Palgunadi, H. Lee, J.Y. Bae, B.S. Ahn, H.S. Kim and S.-H. Lee

Aliphatic polycarbonate synthesis by alternating copolymerization of carbon dioxide with cyclohexene oxide using heterogeneous zinc complex

I. Kim, M.J. Yi, S.H. Pyun, D.W. Park and C.-S. Ha

Alternating copolymerization of carbon dioxide and epoxide [1]

Aluminum Schiff base complex – quartenary ammonium salt systems as novel initiators

H. Sugimoto, H. Ohtsuka and S. Inoue

Alternating copolymerization of carbon dioxide and epoxide [2]

The first example of polycarbonate synthesis from 1-atm carbon dioxide by manganese porphyrin

H. Sugimoto, H. Ohshima and S. Inoue

Semifluorinated block copolymer surfactants for water-in-CO₂ microemulsions

K.T. Lim, H.J. Kim, S.-H. Jin, S.-J. Choi and Y.S. Gal

Aliphatic polycarbonate synthesis by alternating copolymerization of carbon dioxide with cyclohexene oxide using -diiminate zinc complex

S.M. Kim, I. Kim, D.W. Park and C.-S. Ha

Synthesis of poly(DOMA-co-AN) by addition of carbon dioxide to poly(GMA-co-AN) and the miscibility behavior of its blends with PEI

J.-H. Hur, D.-O. Lim, K.-H. Kim, I. Kim, H.-C. Woo and D.-W. Park

Half-sandwich complexes with dihydroxy polypyridine: water-soluble, highly efficient catalysts for hydrogenation of bicarbonate attributable to electron-donating ability of oxyanion on catalyst ligand

Y. Himeda, N. Onozawa-Komatsuzaki, H. Sugihara, H. Arakawa and K. Kasuga

Synthesis of propylene carbonate from carbon dioxide and propylene oxide using ionic liquids

D.-W. Park, J.-H. Hur, E.-S. Jeong, S.-W. Park and I. Kim

III. Electro and photocatalytic reduction of CO₂

Spectroscopic characterization of intermediates in CO₂ reduction with rhenium photocatalysts

E. Fujita, Y. Hayashi, S. Kita and B.S. Brunschwig

Electrochemical reduction of CO₂ at alloy electrode in methanol

S. Kaneco, H. Yamauchi, H. Katsumata, T. Suzuki and K. Ohta

Photoactivation of Ti centers in mesoporous silicate sieve under visible and UV light

W. Lin and H. Frei

Photocatalytic reduction of CO₂ with H₂O on Ti-containing mesoporous silica hydrophobically modified using fluoride ions

H. Yamashita, M. Okazaki, K. Ikeue and M. Anpo

Effect of CO₂ concentration on growth and photosynthesis of spirulina platensis

S.-G. Kim, C.-S. Park, Y.-H. Park, S.-T. Lee and H.-M. Oh

High performance photocatalytic reduction of CO₂ with H₂O by TiSBA-15 mesoporous material

J.-S. Hwang, J.-S. Chang, S.-E. Park, K. Ikeue and M. Anpo

IV. CO₂ as oxidant

New CO₂ chemistry – recent advances in utilizing CO₂ as an oxidant and current understanding on its role

S.-E. Park and J.S. Yoo

Tri-reforming of methane over Ni catalysts for CO₂ conversion to syngas with desired H₂/CO ratios using flue gas of power plants without CO₂ separation

C. Song, W. Pan, S.T. Srimat, J. Zheng, Y. Li, Y.-H. Wang, B.-Q. Xu and Q.-M. Zhu

CO₂ dehydrogenation of propane over Cr-MCM-41 catalyst

K. Takehira, Y. Oishi, T. Shishido, T. Kawabata, K. Takaki, Q. Zhang and Y. Wang

CO₂ reforming of n-heptane on a Ni/Al₂O₃ catalyst

K.J. Puolakka and A.O.I. Krause

Dehydrogenation of ethylbenzene over promoted vanadium oxide catalyst with carbon dioxide: from laboratory to bench-scale test

D.-Y. Hong, S.H. Jhung, J.-M. Lee, M.-S. Park, J.-S. Chang and S.-E. Park

Oxidative dehydrogenation of ethane with carbon dioxide over chromium oxide catalysts

M. Ji, D.-Y. Hong, J.-S. Chang, V.P. Vislovskiy, J.S. Yoo and S.-E. Park

Oxidehydrogenation of ethane with CO₂ over transition metal doped MCM-41 mesoporous catalysts

Y.-L. Bi, V.C. Corberán, H. Zhuang and K.-J. Zhen

Selective formation of styrene via oxidative dehydrogenation of 4-vinylcyclohexane over ZrO₂-supported iron oxide catalysts

J.-S. Chang, D.-Y. Hong, Y.-K. Park and S.-E. Park

Catalytic transformation of cyclohexanol over mixed metal oxides with and without CO₂

V.R. Chumbhale, J.S. Kim, S.B. Lee and M.J. Choi

V. Studies in supercritical CO₂

The utility of carbon dioxide in homogeneously-catalyzed organic synthesis

P.G. Jessop

Aldol reactions of propanal using MgO catalyst in supercritical CO₂

K. Matsui, H. Kawanami and H. Hayashi

Critical point and phase envelope calculations - Some practical aspects based on CO₂-mixteres

H.A. Turunen, J.-P. Pokki, R. Raudaskoski, E. Turpeinen, E. Muurinen, K.I. Keskinen and R.L. Keiski

Evaluation of sequesterable carbon dioxide in japanese coal samples at sub-critical and supercritical conditions

M. M. Toribio, Y. Oshima and S. Shimada

Synthesis and characterization of poly(styrene-co-butyl acrylate) and poly(styrene-co-butyl methacrylate) in supercritical carbon dioxide

B. Shin, W. Bae, H. Lee and H. Kim

Phenol hydrogenation over supported metal catalysts under supercritical carbon dioxide

C.V. Rode, U.D. Joshi, T. Sato, O. Sato and M. Shirai

Synthesis of various block copolymers containing poly(L-lactide) in supercritical carbon dioxide

H.S. Hwang, E.J. Park, Y.T. Jeong, H. Heo and K.T. Lim

Vapour pressure of CO₂ as well as phase envelopes and critical points for CO₂ and CH₄ mixtures calculated by Aspen Plus and Flowbat simulation software

R. Raudaskoski, E. Turpeinen, H. Turunen, K. Rahkamaa-Tolonen and R.L. Keiski

VI. CO₂ separation and recovery

CO₂ recovery pilot plant

K.R. Jang, J.H. Kim, J.G. Shim, Y.M. Ahn and H.M. Eum

A 2-stage PSA process for the recovery of CO₂ from flue gas and its power consumption

S.-H. Cho, J.-H. Park, H.-T. Beum, S.-S. Han and J.-N. Kim

Novel nanoporous “Molecular basket” adsorbent for CO₂ capture

C. Song, X. Xu, J.M. Andresen, B.G. Miller and A.W. Scaroni

Reversible adsorption of carbon dioxide on amine-modified SBA-15 from flue gas containing water vapor

N. Hiyoshi, K. Yogo and T. Yashima

Hollow fiber membrane contactor hybrid system for CO₂ recovery

K.-H. Lee, S.-H. Yeon, B. Sea and Y.-I. Park

Optimization of CO₂ absorption process with MEA solution

S. Kim, H.-T. Kim and B.-C. Choi

Permeability modification for CO₂ EOR

G. Tian, C. Tao, R. Qu, W. Han, J. Deng and P. Behrenbruch

Catalytic reactivity for the formation of dimethyl ether from synthesis gas over hybrid catalysts

W.-S. Ju, C.W. Choi, S.-H. Lee, W. Cho, J.-S. Hwang, S.-E. Park and Y.-S. Baek

VII. Biology and biochemistry of CO₂ utilization

Design and experimental practice of photobioreactor incorporating microalgae for efficient photosynthetic CO₂ fixation performance

Y. Watanabe

Biomass Japan strategy

S. Yokoyama

Carbon dioxide removal and biomass production by Anabaena cylindrica IAM M1 using reactor in series

A. Wijanarko and K. Ohtaguchi

Viability and activity of microorganisms in pressurized and supercritical carbon dioxide

B. Zhang, X. Liu and Y. Gan

Novel conversion of carbon dioxide to methanol catalyzed by sol-gel immobilized dehydrogenases

Z. Jiang, S. Xu and H. Wu

Combined thermoneutral processes for CO₂ emission avoidance and fuel saving in the metallurgical and lime industries

M. Halmann and A. Steinfeld

VIII. Utilization of CO₂ hydrates

Greenhouse gas hydrates in the ocean

S.M. Masutani

Replacement of methane hydrate by carbon dioxide: ¹³C NMR study for studying a limit to the degree of substitution

H. Lee, Y. Seo, Y.-T. Seo, D.Y. Kim, I.L. Moudrakovski and J.A. Ripmeester

Continuous CO₂ clathrate hydrate formation by a motionless mixer

H. Tajima, A. Yamasaki and F. Kiyono

A new type separation process of condensable greenhouse gases by the formation of clathrate hydrates

K. Shiojiri, T. Okano, Y. Yanagisawa, M. Fujii, A. Yamasaki, H. Tajima and F. Kiyono

The OACE (Ocean Abyssal Carbon Experiment) research project

R. Kojima, I. Aya, K. Yamane, S. Namie, Y. Nakajima, H. Shirota, P. G. Brewer, E.T. Peltzer, P. M. Haugan, T. Johannessen and R.G.J. Bellerby

Addition of carbon dioxide to phenylglycidyl ether using quaternary ammonium salts grafted on modified MCM-41 support

D.-W. Park, D.-H. Shin, B.-S. Yu, K.-H. Kim, S.-W. Park, I. Kim and J.-W. Lee

Chemical absorption of carbon dioxide with NaOH in non-Newtonian w/o emulsion

S.-W. Park, B.-S. Choi, T.-Y. Kim and J.-W. Lee

CO₂ absorption and regeneration using Na and K based sorbents

S.C. Lee, B.Y. Choi, S.J. Lee, S.Y. Jung, C.K. Ryu and J.C. Kim

Preparation of 6FDA-based polyimide membranes for CO₂ gas separation

K.-J. Kim, W.-W. So and S.-J. Moon

Chemical absorption of carbon dioxide into toluene solution of oxirane

S.-W. Park, D.-W. Park, T.-Y. Kim and J.-W. Lee

A study about CO₂ sbsorption process design for thermal power plant flue gas

S.-Y. Park, B.-M. Min, J.-S. Lee and H.-M. Eum

Membrane/PSA hybrid process for carbon dioxide recovery at low concentration

J.-K. Jeon, S.-K. Ihm, Y.-K. Park, J.S. Kim, J.-I. Dong, S. Kim, J.M. Kim, S.-S. Kim and K.-S. Yoo

Effect of isotherm selection on performance prediction of CO₂ PSA process

J.-K. Jeon, S.-K. Ihm, Y.-K. Park, J.S. Kim, S.D. Kim, S. Kim, J.M. Kim, S.-S. Kim and K.-S. Yoo

Chemical absorption of carbon dioxide with AMP in aqueous PAA solution

S.-W. Park, B.-S. Choi, H.-I. Jung and J.-W. Lee

IX. General uses of CO₂

The role of CO₂ fixation in the strategy for mitigating global warming

Y. Kaya

The preparation of metallic tungsten and flower-like structure tungsten materials with using CO/CO₂ mixtures

J.-D. Lee, D.H. Lee, N.K. Park, S.O. Ryu, W.C. Chang and T.J. Lee

On-line gas chromatographic analysis of CO₂ hydrogenation products

M. Reinikainen and M. Niemelä

Synthesis of ultrafine TiO₂ particles from hydrolysis of Ti(OⁱPr)₄ with PEO-b-PFOMA reverse micelles in CO₂

K.T. Lim, H.S. Hwang, S.-S. Hong, C. Park, W. Ryoo and K.P. Johnston

Synthesis of propylene carbonate from urea and propylene glycol

Q. Li, N. Zhao, W. Wei and Y. Sun

Dissolution behavior of liquid CO₂ droplets injected at the intermediate ocean depth in Clarion-Clipperton

C.-B. Kim and N.-J. Kim

Growth and carbon fixation of cyanobacterium spirulina platensis with different nitrogen sources

A. Choi, B.-D. Yoon, H.-S. Kim and H.-M. Oh

Author index

Keyword index

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